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5. An Efficient System TiCl4-Al for the Homocoupling Reaction of Aromatic Aldehydes

An Efficient System TiCl4-Al for the Homocoupling Reaction of Aromatic Aldehydes

来源 :高等学术化学研究 | 被引量 : 0次 | 上传用户：zhuzhugugulili

【摘 要】

：

The reduction of TiC14(THF)2 with Al in CH2Cl2 gave a green solution of [Ti2(μ-Cl)2Cl4 ·(THF)4] (1) which was found to promote the reductive homocoupling of a

【作 者】

：

LI Ting-you WANG Li-ping CUI W 

【机 构】

：

College of Life Science

【出 处】

：

高等学术化学研究

【发表日期】

：

2004年期

【关键词】

：

Pinacol coupling reaction Aromatic aldehyde Diastereoselectivity 

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The reduction of TiC14(THF)2 with Al in CH2Cl2 gave a green solution of [Ti2(μ-Cl)2Cl4 ·(THF)4] (1) which was found to promote the reductive homocoupling of aromatic aldehydes toyield symmetrical 1,2-diols with high diastereoselectivities.

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