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μ-氧代双核金属卟啉是一类具有生物活性的化合物,它们能模拟细胞色素p-450在温和条件下催化亚碘酰苯对惰性碳氢键的单充氧化反应,因而对它们的研究是非常有意义的。稳定的μ-氧代双铁(III)卟啉和μ-氧代双铬(III)卟啉已被合成,人们一直期望能获得具有类似结构的μ-氧代双锰(III)卟啉。Groves等人在-50℃由TPPMn~(III)Cl与PhlO反应得到了高价双锰卟啉化合物[C1Mn~(IV)TPP(OIPh)]_2O,这类高价双锰卟啉在室温下不稳定,迅速分解为单锰(III)卟啉。关于稳定的μ-氧代双锰(III)卟啉,至今还未见文献报道。
μ-oxobinuclear metalloporphyrins are a class of biologically active compounds that mimic cytochrome p-450 under mild conditions to catalyze the singly-oxidative reaction of iodosylbenzenes with inert hydrocarbon bonds, and thus their investigation It is very meaningful. The stabilized μ-oxobis (III) porphyrin and μ-oxybischromium (III) porphyrin have been synthesized, and it has been expected that μ-oxobismuth (III) porphyrin with a similar structure will be obtained. Groves and others at -50 ℃ by TPPMn ~ (III) Cl with PhlO obtained high-price bi-manganese porphyrin compound [C1Mn ~ (IV) TPP (OIPh)] _ 2O, such high price of bismuth porphyrin at room temperature instability , Quickly decomposed into single manganese (III) porphyrin. About the stable μ-oxo bismuth (III) porphyrin, has not been reported in the literature.