The mixing technology of laser and heated nitrogen was applied to improve the surface hardness of titanium alloy (TC4). The samples were nitrided with laser power density 0f 6.5×105W·cm-2, the scanning speed various from 100 to 500mm · mm-1. The nitrogen gas was pre-heated to 300℃ to accelerate the nitriding process. Some interested samples were tested with XRD method (X-ray diffraction) to analyze the composition of nitrides, and the surface hardness of HV was measured. The results show that TiN and Ti2N were formed on the surface of Ti alloy with proper nitriding parameters, but TiN is the main composition. The surface hardness increased by three times, which is from the original value of 269 to 794kg· mm -2. The mechanism of the mixing technology is considered mainly of the activation of nitrogen by laser power and the pre-heated process which accelerated the nitriding process. The nitridation process can be considered as six steps given in detail. The result by analyzing the mechanism of improving the surface property of TiAl alloy shows the improvement of surface property due to two factors: the first reason is the result of laser annealing, and the second one is the formation of TiN. The mixing technology of laser and heated nitrogen was applied to improve the surface hardness of titanium alloy (TC4). The samples were nitrided with laser power density 0f 6.5 × 10 5 W · cm -2, the scanning speed various from 100 to 500 mm · mm- 1. The nitrogen gas was pre-heated to 300 ℃ to accelerate the nitriding process. X-ray diffraction (X-ray diffraction) to analyze the composition of nitrides, and the surface hardness of HV was measured. show that TiN and Ti2N were formed on the surface of Ti alloy with proper nitriding parameters, but TiN is the main composition. The surface hardness increased by three times, which is from the original value of 269 to 794 kg · mm -2. of the mixing technology is considered primarily of the activation of nitrogen by laser power and the pre-heated process which accelerated the nitriding process. The nitridation process can be considered as six steps given in detail. The result by analyzing the Mechanism of improving the surface property of TiAl alloy shows the improvement of surface property due to two factors: the first reason is the result of laser annealing, and the second one is the formation of TiN.