论文部分内容阅读
用~（１３）Ｃ和~１ＨＮＭＲ波谱，探讨了聚环氧氯丙烷（ＰＥＰＣＨ）的辐射效应，结果表明随着辐射剂量的增加，本体聚合物的~（１３）ＣＮＭＲ谱中各基团的分辨率得以提高，~１ＨＮＭＲ谱中出现了裂解产物共振峰，Ｔ~１变短，表明ＰＥＰＣＨ在限量空气氛中的辐射效应以大分子裂解反应为主，并通过特性粘度的测定，得到了证实。
The radiation effects of polyepichlorohydrin (PEPCH) were investigated by ~ (13) C and ~ 1HNMR spectroscopy. The results showed that the resolution of each group in ~ (13) CNMR spectra of bulk polymers increased with the increase of radiation dose The results show that the cleavage product resonance peak appears in ~ 1HNMR spectrum and T ~ 1 becomes shorter, which indicates that the radiation effect of PEPCH is dominated by macromolecular cleavage reaction and confirmed by intrinsic viscosity measurement.