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一种新颖的钯(Ⅰ)-铑(Ⅱ)异双核配合物 Trans-(NC)_2[(CH_3O)_3P]Rh(μ-dppm)_2Pd(Cl)(其中dppm 为双(二苯基膦)甲烷)已经合成,它在配位化学和金属簇化学及催化机理的研究中具有典型意义.这个配合物的分子结构已由 X 射线单晶衍射测出,纠正了文献[1]中的错处,并揭
A novel palladium (Ⅰ) -rhodium (Ⅱ) heterobinuclear complex, Trans- (NC) _2 [(CH_3O) _3P] Rh (μ-dppm) _2Pd (Cl) Methane) has been synthesized, which has a typical significance in the study of coordination chemistry and the chemistry and catalysis of metal clusters.The molecular structure of this complex has been detected by X-ray single crystal diffraction and the errors in [1] And expose