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碳氟等离子体聚合物结构的ESCA表征,一般运用电荷电位模型,经过量子化学计算,对ESCA谱的C_(15)峰作特定官能基团的归属,此方法运算复杂。Ginnard运用Pauling方法尝试在含有不同取代基的碳原子电负性和该原子1s电子结合能位移之间建立线性关系,对
The ESCA characterization of fluorocarbon plasma polymer structure generally uses the charge potential model. Quantum chemical calculation is used to assign the C_ (15) peak of ESCA spectrum to a specific functional group. This method is computationally complicated. Ginnard used Pauling’s method to try to establish a linear relationship between the electronegativity of carbon atoms with different substituents and the 1s bond shift of the atom.