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The reactions of (NH4)2MoO2S2 with Cu(PPh3)3Cl in CH3CN in the air, or with CuCl, Ph4PBr, and NaS2CNEt2 in DMF under anaerobic condition, afforded the cluster complexes MoS3OCu2 (PPh3)3 (Ⅰ) and (Ph4P)2 CMo2Cu5S6O2-(S2CNEt2)33 · DMF (Ⅱ), respectively. Compound (Ⅰ), MoOS3Cu2P3C54H45(Mr = 1121. 0) , crystallizes in the triclinic, space group P1 with cell parameters a = 14. 103 (3), b = 17.906(3), c=11.503(2)(?), α=107. 76(1), β=111.81(2), γ = 74.93 (2)°, F = 2532. 9(?)3 and Z=2, Dc=1. 471 g/cm3, F (000) = 1140, μ(MoKα) = 13. 215 cm-1, final R = 0. 060 (Rw = 0.064) for 5959 independent reflections with I >3σ(Ⅰ). Complex (IⅡ), Mo2O3S12Cu5P2N4C66H77 (Mr = 1930. 67) , crystallizes in monoclinic, space group P2/c with cell parameters a = 25. 325(19) , 6 = 22. 506(9) , c =14. 066(8)(?) , β =100. 96(6)°, V =7871. 16 (?)3, Z = 4, D,= 1. 629 g/cm3, F(000) = 3904, μ(MoKα) = 20. 216 cm-1, R = 0. 097 (Rw = 0. 095) for 5677 reflections with I>3σ(Ⅰ). The core structure of complex (Ⅰ) is defective cub
The reactions of (NH4) 2MoO2S2 with Cu (PPh3) 3Cl in CH3CN in the air, or with CuCl, Ph4PBr, and NaS2CNEt2 in DMF under anaerobic condition, afforded the cluster complexes MoS3OCu2 (PPh3) 3 (3), b = 0, crystallizes in the triclinic, space group P1 with cell parameters a = 14. 103 (3), m = 17.906 (3), c = 11.503 (2) (?),? = 107.76 (1),? = 111.81 (2),? = 74.93 (2) °, F = 2532.9 = 2, Dc = 1. 471 g / cm3, F (000) = 1140, μ (MoKα) = 13. 215 cm -1, final R = 0.060 (Rw = 0.064) for 5959 independent reflections with I> 3σ (Ⅰ). Complex (IⅡ), Mo2O3S12Cu5P2N4C66H77 (Mr = 1930. 67), crystallizes in monoclinic space group P2 / c with cell parameters a = 25. 325 (19), 6 = 14. 066 (8) (?), Β = 100.96 (6) °, V = 7871.16 (?) 3, Z = 4, D, = 1.6229 g / cm3, F , μ (MoKα) = 20. 216 cm -1, R = 0. 097 (Rw = 0.095) for 5677 reflections with I> 3σ (Ⅰ). The core structure of compl ex (Ⅰ) is defective cub