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模拟研究15-5PH不锈钢在6%FeCl_3溶液中浸泡不同时间的初期点蚀规律,采用电化学阻抗测试和扫描Kelvin探针技术研究15-5PH不锈钢初期点蚀过程中的电化学行为。结果表明,随着浸泡时间增长,电化学反应电阻和阻抗模值逐渐减小,EIS谱由一个时间常数逐渐变成两个明显的时间常数.随着腐蚀的不断进行,不锈钢表面阴极区和阳极区不断发生变化,呈现局部腐蚀的特征,表面电位也逐渐升高,阴极区和阳极区变得明显,腐蚀反应处于加速过程。
The initial pitting corrosion of 15-5PH stainless steel immersed in 6% FeCl_3 solution for different periods was simulated. The electrochemical behavior of 15-5PH stainless steel during initial pitting corrosion was studied by electrochemical impedance spectroscopy and scanning Kelvin probe technique. The results show that the EIS spectrum gradually changes from a time constant to two obvious time constants as the soaking time increases, and the electrochemical reaction resistance and impedance modulus decrease gradually. As the corrosion progresses, the surface of the stainless steel cathode and the anode The area is constantly changing, showing the characteristics of local corrosion, the surface potential is gradually increased, the cathode area and the anode area become obvious, the corrosion reaction in the acceleration process.