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Two new coordination polymers,[M_6L_3(DMA)_3(H_2O)](M=Zn for 1,Cu for 2,L=tetrakis[3-(carboxyphenyl)oxamethyl]methane acid,DMA = N,N-dimethylacetamide) have been solvothermally synthesized. Single-crystal X-ray diffraction analysis reveals that compounds