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含铋金属氧簇结构的多样性和多功能性使其在诸多领域有着非常广泛的应用。本文总结了已报道的50多个含铋金属氧簇化合物,根据Bi(Ⅲ)在金属氧簇中所充当的作用,可将含铋金属氧簇分成4大类:(1)Bi(Ⅲ)作为中心杂原子;(2)Bi(Ⅲ)作为取代原子;(3)Bi(Ⅲ)作为桥联原子;(4)Bi(Ⅲ)作为终端原子,分别对其合成和结构的发展现状进行总结。同时,介绍了含铋金属氧簇在催化、磁性、光学、药物等方面的应用,并对其前景进行了展望。通过本文可以很好了解含铋金属氧簇的合成、性能及发展,对多金属氧簇的拓展研究有重要意义。
Bismuth metal oxygen cluster structure diversity and versatility make it in many fields has a very wide range of applications. This paper summarizes the reported more than 50 bismuth metal oxygen cluster compounds, according to the role of Bi (Ⅲ) in the metal oxygen cluster, the bismuth metal oxygen cluster can be divided into four categories: (1) Bi (Ⅲ) As a central heteroatom; (2) Bi (Ⅲ) as a substitutional atom; (3) Bi (Ⅲ) as a bridging atom; and (4) Bi (Ⅲ) as a terminal atom to summarize their synthesis and structure respectively . At the same time, the application of bismuth metal oxygen cluster in catalysis, magnetism, optics, medicine and so on is introduced, and its prospect is prospected. This article can be a good understanding of the synthesis, properties and development of bismuth-containing metal oxygen cluster, the expansion of the study of the metal oxygen cluster is of great significance.