Synthesis and Solution Properties of Comb-like Acrylamide Copolymers

来源 :Journal of Wuhan University of Technology(Materials Science | 被引量 : 0次 | 上传用户:vbsunboy
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A comb-like acrylamide copolymer (HCJ-1) was synthesized by using aqueous free radical polymerization of acrylamide (AM) as main monomer and ether carboxylate as functional monomer. The copolymers were characterized with FT-IR and SEM. The SEM results show that the molecular structure of copolymer is extended in salt water. It is proved that the copolymer shows good salt resistance.The solution properties of HCJ-1 were studied and compared with those of partially hydrolyzed polyacrylamide (HPAM). The experimental results show that the obtained HCJ-1, compared with HPAM, exhibits a dramatic enhancement in the salt-resistant properties. The apparent viscosity retention rate of 1.5 g/L HCJ-1 aqueous solution and salt solution after 180 days at 60 ℃ are 70.6% and 64.5%, respectively, exhibiting good thermal stability. In addition, HCJ-1 solution also displays the excellent shearing resistance. In a word, the experimental results show the HCJ-1 is a promising profiling agent for high salinity reservoir. A comb-like acrylamide copolymer (HCJ-1) was synthesized by using aqueous free radical polymerization of acrylamide (AM) as main monomer and ether carboxylate as functional monomer. The SEM results exhibited that the molecular structure of the copolymer is extended in salt water. It is proved that the copolymer shows good salt resistance. The solution properties of HCJ-1 were studied and compared with those of partially hydrolyzed polyacrylamide (HPAM) HCJ-1, compared with HPAM, exhibits a dramatic enhancement in the salt-resistant properties. The apparent viscosity retention rate of 1.5 g / L HCJ-1 aqueous solution and salt solution after 180 days at 60 ° C are 70.6% and 64.5% respectively, exhibiting good thermal stability. In addition, HCJ-1 solution also displays the excellent shearing resistance. In a word, the experimental results show the HCJ-1 is a promising profiling agent for high sali nity reservoir.
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