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The removal of four dissolved organic matter (DOM) fractions,non-acid hydrophobics,hydrophobic acids,hydrophilics and transphilics,was achieved by coagulation-UV/H2O2 oxidation in post-pharmaceutical wastewater (PhWW).Coagulation with Polyferric chloride (PFC),Polymeric ferric sulfate (PFS) and Polymeric aluminum ferric chloride (PAFC) was studied separately to evaluate the effects of the initial pH and coagulant dosage.The coagulation-UV/H2O2 oxidation method resulted in much higher reduction rates for dissolved organic carbon (DOC) (by 75％) and UV254 (by 92％) than coagulation or UV/H2O2 oxidation alone.The proportion of non-acid hydrophobics,hydrophobic acids,transphilics and hydrophilics removed by coagulation was 54％,49％,27％ and 12 ％,while the combined treatment removed 92％,87％,70％ and 39％,respectively.Parallel factor analysis (PARAFAC) of fluorescence measurements revealed that the humic-like fluorescent component C4 showed the highest removal (by 44％) during the coagulation stage.After coagulation-UV/H2O2 treatment,the humic-like fluorescent component C3 had the highest removal (by 72％),whereas xenobiotic organic fluorescent components C1 and C4 remained recalcitrant to decomposition.Significant correlations (R2 ＞ 0.8) between C1 and the hydrophobic acids and non-acid hydrophobics suggested the possibility of using fluorescence spectroscopy as an effective tool to assess variations in DOM fraction treatment efficacy in coagulation-UV/H2O2 systems.After the combined treatment,toxic inhibition of cellular activity by post PhWW decreased from 88％ to 47％ and biodegradability increased from 0.1 to 0.52.