Ultra-high-resolution detection of Pb2 ions using a black phosphorus functionalized microfiber coil

来源 :PhotonicsResearch | 被引量 : 0次 | 上传用户:xxasp
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A black phosphorus (BP) functionalized optical fiber sensor based on a microfiber coil resonator (MCR) for Pb2 ion detection in an aquatic environment is presented and experimentally demonstrated. The MCR-BP sensor is manufactured by winding a tapered microfiber on a hollow rod composed of a low-refractive-index polycarbonate (PC) resin with the BP deposited on the internal wall of the rod. Based on the propagation properties of the MCR, the chemical interaction between the Pb2 ions and the BP alters the refractive index of the ambient environment and thus results in a detectable shift in the transmission spectrum. The resonance wavelength moves towards longer wavelengths with an increasing concentration of Pb2 ions, and the sensor has an ultra-high detection resolution of 0.0285 ppb (parts per billion). The temperature dependence is 106.95 pm/°C due to the strong thermo-optic and thermal-expansion effect of the low-refractive-index PC resin. In addition, the sensor shows good stability over a period of 15 days. The local pH also influences the sensor, with the resonance wavelength shift increasing as pH approaches a value of 7 but then decreasing as the pH value increases further due to the effect of the BP layer by H and OH? ions. The sensor shows the potential for high-resolution detection of Pb2 ions in a liquid environment with the particular advantages of having a simple structure, ease of fabrication, low cost, low loss, and simple interrogation.
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