【摘 要】
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Fluorescent intelligent materials have attracted wide attention because of their great potential applications.One major hurdle for the development and application of fluorescent intelligent materials is the aggregation-caused quenching effect in the solid
【机 构】
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Department of Chemistry,Hong Kong Branch of Chinese National Engineering Research Center for Tissue
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Fluorescent intelligent materials have attracted wide attention because of their great potential applications.One major hurdle for the development and application of fluorescent intelligent materials is the aggregation-caused quenching effect in the solid state.Herein,tetraphenylethylene-based trithiocarbonate polymers with satisfactory molecular weights (Mw up to 24900) were synthesized through a one-pot polymerization route under mild conditions.The polymers were non-emissive due to the quenching effect of the trithiocarbonate group.However,upon UV irradiation,the polymers degraded and strong emission from the tetraphenylethylene unit was observed.Such a unique property endows them with great potential applications,such as photopatterning,anti-counterfeit la-bels,and UV detection.
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