HNIW/FOX‑7基高能低易损性PBX的老化性能

来源 :含能材料 | 被引量 : 0次 | 上传用户:lily009009
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
为研究炸药老化后对武器可靠性和安全性的影响,按照GJB736.8‑90火工品试验方法71 ℃试验法对HNIW/FOX‑7基高能低易损性压装PBX进行了7、14、21 d以及28 d的老化试验。对老化前后PBX造型粉的表观形貌和热分解性能进行了表征,且对造型粉进行了FTIR和XRD测试,测定了PBX药柱老化前后的尺寸和质量变化率及力学性能变化。结果表明,老化后HNIW/FOX‑7基PBX药柱仍有效,质量变化率和尺寸变化率均小于1%,符合美军标MIL‑STD‑1751的评价标准;老化PBX造型粉表面形貌随着老化时间增加,裂纹增多,不平整;但PBX造型粉的分子结构和晶型未改变;随着老化时间的增加,其活化能下降都不超过10%,具有较好的热稳定性;老化7、14、21 d以及28 d后HNIW基PBX的抗压强度(σc)分别增加3.18、3.40、3.67 MPa和3.79 MPa,弹性模量(E)分别增加0.65、0.79、0.91 GPa和0.96 GPa,σc、E的变化率与老化时间成正相关,经老化试验后PBX药柱的抗压强度增加。“,”The HNIW/FOX‑7‑based PBX has been aged 7, 14, 21 d and 28 d at 71 ℃ according to GJB736.8-90 initiators and pyrotechnics test method, respectively. And the morphology and thermal decomposition properties of PBX molding powder before and after aging were characterized. The PBX molding powder was tested by FTIR and XRD. The variations of size, mass and mechanical properties of the PBX columns have been measured before and after aging tests. Results show that the mass and size change rate are both within 1%, which meets the evaluation standard of MIL‑STD‑1751, indicating that PBX columns are still at an acceptable level after aging tests. The surface morphology of PBX molding powders has changed in varying degrees. There are more surface cracks and the surface morphology are more uneven with the increase of aging time. Moreover, FTIR and XRD results indicate that the molecular structure and crystal form of HNIW/FOX‑based PBX have not changed after aging tests. Besides, the analyses of thermal decomposition performance show that the thermal decomposition activation energy of PBX molding powders have decreased after aging tests with the decreases of -5.23%, -5.88%, -7.00% and -8.23%, respectively, which demonstrates that PBX still has good thermal stability after aging tests. The results of mechanical properties show that the compressive strength of HNIW/FOX‑7‑based PBX increases by 3.18, 3.40, 3.67 MPa and 3.79 MPa, respectively, and the modulus increases by 0.65, 0.79, 0.91 GPa and 0.96 GPa respectively after aging for 7, 14, 21 d and 28 d. Therefore, the change rate of compressive strength and elastic modulus of PBX columns are positively correlated with the aging time, indicating that the compressive strength of PBX columns increases after aging test.
其他文献
请下载后查看,本文暂不支持在线获取查看简介。 Please download to view, this article does not support online access to view profile.
出生于1953年8月24日的山姆·托兰斯(Sam Torrance)有着双重身份,不仅是苏格兰著名的职业球员,如今更是转型成为一名优秀的高尔夫评论员。从1970年到1990年,他是欧巡赛上的领
2012年10月14日,2012年南山·中国大师赛在山东南山丹岭翠园高尔夫球场降下帷幕,令人难以忘怀的是,跌宕起伏的5洞加洞赛让在场观众过足了球瘾,高潮迭起的争夺令人窒息,是近年
针对如何调整现场正在使用的进口5辊矫直机上辊系各矫直辊压下量,以解决合理矫直带钢的问题,结合该矫直机双偏心调整的特点,从解析角度分析了2个偏心轴转角的角度变化对上辊
请下载后查看,本文暂不支持在线获取查看简介。 Please download to view, this article does not support online access to view profile.
期刊
2012年1月12日,广发银行倾情举办的2011—2012“广发杯”高尔夫球精英赛(广州站)在广州南海桃园高尔夫俱乐部圆满收杆。经过18洞角逐,叶新隆以74杆成绩问鼎“广发杯”精英赛
泵-蓄势器传动的液压机,由于采用了蓄势器,故只用流量较小的高压泵。在压机工作的间歇时间将工作液体储存在蓄势器中,当工作需要的时候,再由蓄势器和高压泵同时供给工作缸,工
本文以秦皇岛港杂货港务公司散粮站运输存储控制系统为例,探讨了大型散粮筒仓流程选择的方法和控制系统的控制方法。 In this paper, Qinhuangdao Port Groceries Grain Tra
出身于武术世家的陈同山,不仅培养出了自己的儿子、“功夫明星”释小龙,还要培养出数以万计的武术影视人才,在影视界弘扬少林功夫。见到陈同山时,他刚从郑州风尘仆仆回来。近
采用振动成型法设计水泥稳定碎石级配,能准确模拟现场碾压方式。通过实体工程的应用,介绍了振动成型水泥稳定碎石的施工工艺。检测结果表明,振动成型法设计的水泥稳定碎石无