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合成了三氨基胍三硝基间苯二酚盐(TAGH)2(TNR)(TAG:三氨基胍;TNR:2,4,6-三硝基间苯二酚),并对其进行了元素分析及红外光谱表征.利用X射线单晶衍射分析测定了其晶体结构.该晶体属于单斜晶系,空间群为C2/c,晶体学数据为,a=2.2892(6)nm,b=1.2802(3)nm,c=1.3661(4)nm,!=111.174(5)°,V=3.7333(16)nm3,Z=8.该化合物是由二个C(N2H3)3+与一个(C6HN3O8)2-相结合而成的离子型化合物.用差示扫描量热法、热重法和微商热重法研究了该化合物的热分解过程,研究结果表明,在10K·min-1的升温速率下,该化合物只有一个剧烈的放热分解过程,该过程发生在450.1-477.7K之间,且分解产物主要是气体产物.
Triaminoguanidine trinitro-resorcinol salt (TAGH) 2 (TNR) was synthesized (TAG: triaminoguanidine; TNR: 2,4,6-trinitro resorcinol) The crystal structure of the crystal belongs to the monoclinic system with C2 / c space group and its crystallographic data is a = 2.2892 (6) nm, b = 1.2802 (3) nm, c = 1.3661 (4) nm, = 111.174 (5) °, V = 3.7333 (16) nm3 and Z = 8. The compound is composed of two C (N2H3) 3+ and one (C6HN3O8) 2-, the thermal decomposition process of the compound was studied by differential scanning calorimetry, thermogravimetry and differential thermal analysis.The results show that at a heating rate of 10K · min-1 , There is only one intense exothermic decomposition of the compound, which takes place between 450.1 and 477.7 K and the decomposition products are mainly gaseous products.