【摘 要】
：
The polyoxoanion incorporated {Mn(CO)3+} complex,(n-Bu4N)2[Mo6O16(OCH3)2{HOCH2C(CH2O)3}2{Mn(CO)3}2](1),has been synthesized by the reaction of (n-Bu4N)4[MosO26]
【机 构】
：
Institute of Molecular and Crystal Engineering
论文部分内容阅读
The polyoxoanion incorporated {Mn(CO)3+} complex,(n-Bu4N)2[Mo6O16(OCH3)2{HOCH2C(CH2O)3}2{Mn(CO)3}2](1),has been synthesized by the reaction of (n-Bu4N)4[MosO26] with Mn(CO)sBr in methanol,in the presence of C(CH2OH)4.The complex 1 has been characterized by IR UV-Vis,X-ray single crystal diffraction,and TG.Crystal data for the complex 1:C25H48MnMo3NO16 (1),Triclinic P1,a=0.9405(3) nm,b=1.3351 (4) nm,c=1.5455(4) nm,a=103.206(5)°,β=102.165(5)°,γ=100.784(5)°,V=1.7896(9) nm3,Z=2,R1=0.0703,wR2 = 0.1495.The structure analysis of complex 1 shows that the complex consists of two tetrabutylammonium cations and a polyoxomolybdate anion that incorporates two fac-Mn(CO)3+ units.The anion of complex 1 can be considered as the dimer of two rhomb-like anions by sharing of two comers.
其他文献
The fractionated crystallization behavior of the minor dispersed HDPE phase in PS/POE/HDPE/SBS quaternaryblends was investigated by differential scanning calori
The title compound α,α'-bis(3,5-bismethyl-pyrozole-N-yl)-carbene-acetyl-isopro-penyl hydrazine (C16H22N6O, Mr = 314.40) has been prepared. It was characterize
The mixing of particulates such as powders is an important process in many industries including pharmaceuticals, plastics, household products (such as detergent
The lattice Boltzmann method was used to investigate numerically the fiber orientation distributions in slit channel flows with abrupt expansion for fiber suspe
The authors consider a differentiable manifold with Ⅱ-structure which is an isomorphic representation of an associative, commutative and unitial algebra. For R
A series of imidazo [1,2-a] pyrimidine derivatives substituted adjacently with two aryls at positions 2 and 3 were designed and synthesized in order to improve
Escherichia coli 3-Deoxy-D-manno-octulosonate 8-phosphate(KDO8P) synthase catalyzed the condensation reaction between D-arabinose 5-phosphate(A5P) and phosphoen
In this paper, the authors study the existence of nontrivial solutions for the Hamiltonian systems z(t) = J▽H(t, z(t)) with Lagrangian boundary conditions, whe
Two new compounds were isolated from the 60% ethanol extract of the dried rhizome of Ardisia gigantifolia Stapf. The structures were elucidated on the basis of
A general stochastic model of the atmospheric pressure at the ocean surface was proposed, in which the pressure variation was represented by a spectral decompos