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根据星型低顺式聚丁二烯(LCBR)的溶液性能和线型LCBR的MarkHouwink方程,推导出了星型LCBR的MarkHouwink参数K、α的值,并对不同臂数的星型LCBR进行了GPC分析。结果表明,采用修改后的K、α值估算星型LCBR的GPC谱图中的相对分子质量基本上是可行的。
According to the solution properties of star low cis-polybutadiene (LCBR) and Mark-Hauwink equation of linear LCBR, the Mark-Hauwink parameter K, α of star-shaped LCBR is deduced. Type LCBR GPC analysis. The results show that it is basically feasible to use the modified K, α values to estimate the relative molecular mass in the GPC chromatogram of star LCBR.