【摘 要】
：
A new cadmium complex [Cd(phen)3]·(ClO4)2·(α-FRA)·(H2O)3 was prepared by self-assembly of α-furoic acid, 1,10-phenanthroline (phen), and cadmium perchlorat
【机 构】
：
Department of Chemistry and Materials Science,Department of Chemical Engineering
论文部分内容阅读
A new cadmium complex [Cd(phen)3]·(ClO4)2·(α-FRA)·(H2O)3 was prepared by self-assembly of α-furoic acid, 1,10-phenanthroline (phen), and cadmium perchlorate. It crystal- lizes in the monoclinic system, space group P21/n, with a = 1.28130(15), b = 2.5957(3), c = 1.35449(16) nm, β = 109.395(2)o, V = 4.2492(9) nm3, Dc = 1.491 g/cm3, Z = 4, F(000) = 1926, GOOF = 1.023, the final R = 0.0729 and wR = 0.2086. The crystal structure analysis indicates that the cadmium ion is coordinated with six nitrogen atoms from six 1,10-phenanthroline molecules, giving a distorted octahedral coordination geometry. The cyclic voltametric behavior of the com- plex was also investigated.
其他文献
Aspartie acid and glutamic acid with protected α-amino and α-carboxyl groups had been used to react with the activated hydroxyl group of N-substituted 3,4-fuU
The title compound (E)-2-[(4-tert-butyl-5-(4-methoxybenzyl)thiazol-2-ylimino)me- thyl]phenol was synthesized by the reaction of 5-(4-methoxybenzyl)-4-tert- buty
A new lipophilic monosaccharide,erigearide A(1),was isolated from the aerial parts of Erigeron annuus(Lima.)Pers.Its structure was elucidated by analysis of spe
The reaction of hydrazine hydrate with a new α,γ-diketone ester 3, derived from the reaction of 2,6-dimethyl-3,5-diacetyl-pyridine 2 with diethyl oxalate in t
Regio-and enantioselective reduction of substituted acenaphthenequinones were conducted under mild reaction conditions using plant enzymatic systems.A screening
Two series of 1-(benzoxazole-2-yl)piperazine(8a-i)and 4-(benzoxazole-2-yl)piperidine compounds(10a-i)were designed,synthesized and evaluated for their α1-AR an
Recoverable TiO2 photocatalysis material supported by silicon powder was pre- pared with sol-gel method, afterwards the silica gol and sodium silicate were used
A novel hydroxypolyether blocked polydimethylsiloxane,poly(ethylene oxide)propyl-b-polydimethylsiloxane-b-propyl poly(ethylene oxide)(PEO-b=PDMS-b-PEO)was synth
A heterometallic 4f-5d inorganic-organic metal-isonicotinato hybrid [Gd(C6NO2H5)3-
45 isomers of TinNm (n + m = 5, 6) clusters, including linear, some planar and some stero configurations, have been predicted by density functional theory metho