【摘 要】
：
A new heterometallic complex K2[{Eu(H2O)4}2{FeII(bipy)(CN)4}4]·9H2O·CH3OH [bipy=2,2’-bipyridine] was synthesized. The compound has been characterized by X-ra
【机 构】
：
Department of Chemistry, Yunnan University, Kunming, Yunnan 650091, China ,Department of Chemistry,
【出 处】
：
Chinese Journal of Chemistry
论文部分内容阅读
A new heterometallic complex K2[{Eu(H2O)4}2{FeII(bipy)(CN)4}4]·9H2O·CH3OH [bipy=2,2’-bipyridine] was synthesized. The compound has been characterized by X-ray structure analysis, elemental analyses, IR spectrum, TGA thermogram and magnetic susceptibility. The complex consists of novel one-dimensional ladder structure. The crystal belongs to monoclinic system with a space group P21/c, a =1.3946(4) nm, b=2.0450(6) nm, c=2.9722(8) nm, b=99.025(5), V=8.372(4) nm3, Z=4, Dc=1.562 g·cm-3.
A new heterometallic complex K2 [{Eu (H2O) 4} 2 {FeII (bipy) (CN) 4} 4] · 9H2O · CH3OH [bipy = 2,2’-bipyridine] was synthesized. The compound has been characterized by X -ray structure analysis, elemental analyzes, IR spectrum, TGA thermogram and magnetic susceptibility. The complex consists of novel one-dimensional ladder structure. The crystal belongs to monoclinic system with a space group P21 / c, a = 1.3946 b = 2.0450 (6) nm, c = 2.9722 (8) nm, b = 99.025 (5), V = 8.372 (4) nm3, Z = 4 and Dc = 1.562 g · cm-3.
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