The Steric Effect of trans-(1S,2S)-1-Substituted-2-(N,N-dialkyl- amino)-1-indanol Derivatives as Chi

来源 :中国化学快报 | 被引量 : 0次 | 上传用户：wwqewwqe

【摘要】

：

Optically active trans-(1S,2S)-1-substituted-2-(N,N-dialkylamino)-1-indanol derivatives have been prepared and used in the asymmetric addition of diethylzinc to

【作者】

：

Qian Yong XU Hong Fang YANG Fu

【机构】

：

Northwest Institute of Nuclear Technology,Department of Chemistry,Department of Chemical Engineering

【出处】

：

中国化学快报

【发表日期】

：

2004年期

【关键词】

：

Diethylzinc enantioselective alkylation indanol derivative

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Optically active trans-(1S,2S)-1-substituted-2-(N,N-dialkylamino)-1-indanol derivatives have been prepared and used in the asymmetric addition of diethylzinc to aldehydes to give sec-alcohol in good yield with up to 93.1% enantiomeric excess.

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The Steric Effect of trans-(1S,2S)-1-Substituted-2-(N,N-dialkyl- amino)-1-indanol Derivatives as Chi

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