Anticorrosion behavior of conversion coatings obtained from unbuffered cerium salts solutions on AA6

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:ndspsp
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
The anticorrosive properties of cerium based conversion coatings deposited on AA6061-T6 alloy by immersion in unbuffered cerium chloride and cerium nitrate solutions in the presence of hydrogen peroxide were investigated and characterized by potentiodynamic polarization(PDP) and electrochemical impedance spectroscopy(EIS) in 0.5 mol/L NaCl aqueous solution.The microstructure and chemicalcomposition of the protective films were examined by scanning electron microscopy(SEM) and energy dispersive X-ray spectroscopy(EDS).It was found that the best corrosion protection was afforded by the samples treated during 600 s in cerium chloride solution at pH values~5.5-4,showing higher amounts of cerium and polarization resistance values greater than 10 Ω m2.Moreover,an ennoblement of the corrosion potential and decreasing of the cathodic and anodic currents were obtained compared with the cerium nitrate solutions application.Thisbehavior was attributed to the influence of the deposition parameters such as type of the salt anion,i.e.,chelating effect and chaotropic characteristics,pH fluctuations in the conversion solution and deposition time. The anticorrosive properties of cerium based conversion coatings deposited on AA6061-T6 alloy by immersion in unbuffered cerium chloride and cerium nitrate solutions in the presence of hydrogen peroxide were investigated and characterized by potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) in 0.5 mol / L NaCl aqueous solution. The microstructure and chemical composition of the protective films were examined by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). It was found that the best corrosion protection was afforded by the samples treated during 600 s in cerium chloride solution at pH values ​​~ 5.5-4, showing higher amounts of cerium and polarization resistance values ​​greater than 10 Ω m2.Moreover, an ennoblement of the corrosion potential and decreasing of the cathodic and anodic currents were obtained compared with the cerium nitrate solutions application. This behavior was attributed to the influence of the deposition paramet ers such as type of the salt anion, ie, chelating effect and chaotropic characteristics, pH fluctuations in the conversion solution and deposition time.
其他文献
现代战争主要是信息化战争,美国的某高级指挥官曾经说过:“如果发生第三次世界大战,获胜者必将是最善于控制和运用电磁频谱的一方.”现在军用民用的电子设备都逐渐深入的发展
仔细观察和研究我国现阶段农药市场的经营现状,还是存在着比较多的问题.所以必须要结合实际情况研究出符合当前形势下农药经营者的出路和新的监管方式.
目的探讨不同浓度利巴韦林对家兔外周血细胞的影响规律。方法将雄性家兔30只随机分为A、B、C、D、E5组,每组6只,分别注入利巴韦林5mg/kg、15mg/kg、25mg/kg、35mg/kg及注射生
欧洲议会近日通过提案,将维持对移动设备征收版权税的法令,并可能将征收范围延伸至云服务。现行的《欧盟版权指令》允许基于产品征税,然后将其交给版权所有者,允许通过打印机或智
三月的北京,在全国人大、政协两会队伍中,陡然增加了不少新的网络安全面孔.这其中既包含像严望佳这样连续三届的资深政协委员,也包括新增选的一些代表委员,印证着网络安全在
期刊
新闻宣传,有利于加强党的领导,所以新闻宣传的任务以及责任是十分重大的,不能出现差池.新闻宣传工作对于采编人员的专业能力以及道德素质的要求非常高,因此需要对采编人员进
喝酒的女人不是买醉,是“买癌症”    经常饮酒有可能让我们变成一个肥胖的女人——啤酒是给男人们预备的,而不是给整天想着要让自己变瘦的女人们的。啤酒会让人发胖,全身膨胀,腹中胀气。喝过量的酒会促进胃酸的分泌,严重影响我们的消化功能。如果你的消化系统出现问题,那么食物就不能被身体很好地消化吸收,其直接后果就是造成过食肥胖综合症。更糟糕的是,有一些白酒和非有机葡萄酒含有化学致癌物——乌拉坦。除此以外,
期刊
企业开展创新性统计工作的主要目的就是对企业进行更为有效的科学管理,这不仅是当前企业发展中的重要手段,同时更是石油销售企业制定政策和计划的重要依据.为了在今后的企业
9月7-8日,中国食品科学技术学会主办的“第十五届中国方便食品大会暨方便食品与冷链设备展”在北京举办,此次大会成为行业面对困境,科学家与企业家的一次大规模集结.大会发出