A monitoring method that has been designed for the first time for blast furnace wall with copper staves manufactured in China was introduced. Combining the method of "inverse problem" and the concept "non-inverse problem", the monitoring program for blast furnace wall with copper staves has been realized, which can be used to calculate online the accretion thickness and temperature of hot surface of copper staves after obtaining the values of thermocouples of copper staves. The accretion state obtained in the actual investigation has proved that the result of the program is correct. The monitoring program shows that the accretion would easily fluctuate when the accretion layer is extremely thick or thin, thereby the stable and smooth operation of the blast furnace is hindered. By maintaining appropriate accretion thickness, both long campaigns and high productivity of the blast furnace can be achieved; furthermore, it can also optimize the operation of blast furnace and maximize its production. Approximately 30-50 mm in thickness of accretion layer is maintained on the wall of Shougang blast furnace 2, which can meet the requirement for obtaining both long campaign and high productivity.