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Two new gallium antimony sulfides,[enH2][Ga2Sb2S7]·en(1) and [puH]2[Ga2Sb2S7](2)(en = ethylenediamine,pu = propyleneurea),have been solvothermally synthesized.In the pre-paration of compound 2,the protonated propyleneurea cation as counterion and tem