论文部分内容阅读
合成了一种新的含取代苄基三苯基鏻的马来二氰基二硫烯镍配合物[ClBzTPP]2[Ni(mnt)2].H2O([ClBzTPP]+代表对氯苄基三苯基鏻阳离子,mnt2-代表马来二氰基二硫烯阴离子).配合物为三斜晶系,空间群P墿,晶胞参数为a=1.058 5(2)nm,b=1.108 9(2)nm,c=1.157 0 nm,α=81.98(1)°,β=84.95(1)°,γ=84.45(1)°,V=1.369 1(4)nm3,Z=1,最终一致性因子R=0.058 4.该配合物由2个[ClBzT-PP]+阳离子,1个[Ni(mnt)2]2-阴离子和1个H2O组成.其结构特点是配合物中的[ClBzTPP]+阳离子和Ni(mnt)22-阴离子沿c轴方向堆积成柱,并通过C—H…S,C—H…π,C—H…Ni氢键和π-π堆积作用形成了二维网状结构.
A novel maleated dicyanodithiolene nickel complex [ClBzTPP] 2 [Ni (mnt) 2] containing benzyltriphenylphosphonium was synthesized. H 2 O ([ClBzTPP] + represents p-chlorobenzyltris Phenylphosphonium cation, mnt2- represents maleic dicyanodithioine anion) .The complexes are triclinic with space group P 墿, the unit cell parameters are a = 1.058 5 (2) nm, b = 1.108 9 ( 2) nm, c = 1.157 0 nm, α = 81.98 (1) °, β = 84.95 (1) °, γ = 84.45 (1) °, V = 1.369 1 (4) nm3, Z = 1, final concordance Factor R = 0.058 4. The complex consists of two [ClBzT-PP] + cations, one [Ni (mnt) 2] 2- anion and one H 2 O. Its structure is characterized by [ClBzTPP] + Cations and Ni (mnt) 22- anions accumulate in the c-axis direction into a column and form a two-dimensional network through C-H ... S, C-H ... π, C-H ... Ni hydrogen bonding and π- structure.