【摘 要】
:
One chemical approach using nitric acid as the solvent to decompose thermosetting epoxy resin was discussed The samples were prepared by using different kinds o
【机 构】
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School of Chemical Engineering and Technology,Dept. of Materials Science and Engineering
【基金项目】
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Sponsored by the National Natural Science Foundation of China;教育部新世纪优秀人才支持计划
论文部分内容阅读
One chemical approach using nitric acid as the solvent to decompose thermosetting epoxy resin was discussed The samples were prepared by using different kinds of curing agents,namely polyamide (PA651),isophorone diamine ( IPDA ),4,4-diaminodiphenylmethane (DDM) and 2-ethyl-4-methy-imidazole ( EMI-2,4) and different kinds of epoxy resins,namely bisphenol-A epoxy resin(E-44),bisphenol-A epoxy resin(E-51 ),N,N,N,Nteraglycidy 4,4diaminodiphenyl methane (AG-80) and diglycidyl-4、5-epoxycyclohexane-1,2-dicarboxylate (TDE-g5).Their effects on decomposition rate were investigated and the decomposition products were analyzed by Infra-red (IR) spectra,and Gas Chromatography-Mass Spectrometry (GC-MS).Based on conclusions drawn from experiments,the mechanism of degrading thermosetting epoxy resin with nitric acid was envisaged tentatively.
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