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在液体高分辨ＮＭＲ谱仪上， 测定并比较了具有高效烯烃氢甲酰化活性的水溶性铑膦配合物ＨＲｈ（ＣＯ）（ＴＰＰＴＳ）３ 及与此有关的配体ＴＰＰＴＳ和ＯＴＰＰＴＳ分别在Ｄ２Ｏ、混合溶剂Ｄ２Ｏ－ＴＨＦ（ｄ８）－ＣＤ３ＯＤ中的１Ｈ－ＮＭＲ谱图， 并借助１Ｈ－１Ｈ ＣＯＳＹ谱对上述３ 种化合物的１Ｈ－ＮＭＲ谱峰进行了指认； 讨论了影响化学位移和偶合常数的因素， 为水溶性铑膦配合物催化剂的结构与催化性能的关联及新催化剂设计研究提供了基础数据．
In the liquid high resolution NMR spectrometer, the water-soluble rhodium-phosphine complex HRh (CO) (TPPTS) 3 with high olefin hydroformylation activity and the related ligands TPPTS and OTPPTS were measured and compared in D2O, 1H-NMR spectra of the mixed solvents D2O-THF (d8) -CD3OD and their 1H-NMR peaks were identified by 1H-1H COZY spectrum. Factors affecting the chemical shifts and coupling constants were discussed , Which provided the basic data for the relationship between the structure and catalytic performance of water-soluble rhodium-phosphine complex catalysts and the design of new catalysts.