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用纯水和恒沸点盐酸对六硼酸镁过饱和水溶液进行稀释和酸化,使用激光Raman光谱记录反应过程。对光谱峰进行归属。讨论了溶液中含硼量和pH值对硼氧配阴离子存在形式的影响,对多聚硼氧配阴离子在溶液中的存在形式及其相互作用机理进行了初步探讨。
The supernatant aqueous solution of magnesium hexaborate was diluted and acidified with pure water and azeotropic hydrochloric acid, and the reaction process was recorded by laser Raman spectroscopy. Peak assignments to spectra. The effects of boron content and pH value in the solution on the existence of boron-oxygen anions were discussed. The existing forms and interaction mechanisms of poly-boron oxy anions in solution were also discussed.