Miscibility of Semi-flexible Thermotropic Liquid Crystalline Copolyesteramide with Polyamide 66

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Liquid crystalline polymer-polyamide 66 (LCP/PA66) blends were compounded by usingaBrabender mixing followed by compression moulding. The LCP employed was a semi-flexible liquid crystalline copolyesteramide based on 30% (molar fraction) of p-amino benzoic acid (ABA)and 70% (molar fraction) of poly (ethylene terephthalate)(PET). The LCP/PA66 blends wereinvestigated in terms of the thermal and dynamic mechanical properties. It was found that PA66and LCP components of the blends are miscible in the molten state, but are partially miscible inthe solid state. The inclusion of the semi-flexible LCP into PA66 retards the crystallization rateof PA66. Furthermore, the melting temperature and the degree of crystallinity of PA66 are reduced considerably due to the LCP addition.
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