Synthesis and Crystal Structure of O-Ethyl-N- (2,3,4-tri-O-acetyl-β-D-xylopyranosyl)-thiocarbamate

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The crystal and molecular structures of O-ethyl-N-(2,3,4-tri-O-acetyl-β-D-xylopyranosyl)-thiocarbamate were determined by X-ray crystallography. It crystallizes in the orthorhombic system with space group P2(1)2(1)2(1), lattice parameters a=0.90636(18) nm, b=0.94716(19) nm, c=2.1855(4) nm, V=1.8762(7) nm 3, and Z=4. All the substituents are in equatorial positions. There are four intramolecular interactions, each forming a five-membered ring. The molecules are linked by interactions to form three-dimensional framework. Atoms O6 and O8 show positional disorder. The crystal and molecular structures of O-ethyl-N- (2,3,4-tri-O-acetyl-β-D-xylopyranosyl) -thiocarbamate were determined by X-ray crystallography. It crystallizes in the orthorhombic system with space group Lattice parameters a = 0.90636 (18) nm, b = 0.94716 (19) nm, c = 2.1855 (4) nm, V = 1.8762 (7) nm 3, and Z = 4. All the substituents are in equatorial positions. There are four intramolecular interactions, each forming a five-membered ring. The molecules are linked by interactions to form three-dimensional framework. Atoms O6 and O8 show positional disorder.
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