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The title complex [Cu(L1)(L2)(H2O)]·H2O(1,HL1 = N-(imino(pyridin-2-yl)me-thyl)picolinamidine),HL2 = salicylic acid) has been obtained by volatilization method with L1 prepared from 2,4,6-tripyridyl-1,3,5-triazine in situ.1 was fully characterized by