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A new Cd(Ⅱ) coordination polymer, namely {Cd_2(L)(biimpy)(H_2O)}_n(1, H4 L = 3-(3?,5?-dicarboxylphenoxy)phthalic acid, biimpy = 2,6-bis(1-imdazoly)pyridine), has been successfully synthesized via the hydrothermal reactions of Cd(Ⅱ) ions, H_4L and biimpy.