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合成了配体Ｎ，Ｎ’－双（８－喹啉基）丙二酰胺（ｑｍａＨ＿２），Ｎ，Ｎ’－双（２－羟基苯基）丙二酰胺（ｈｐｍａＨ＿４）及其金属配合物［Ｍ＝Ｃｕ（Ⅱ）、Ｎｉ（Ⅱ）、Ｃｏ（Ⅲ）、Ｐｄ（Ⅱ）、Ｚｎ（Ⅱ）］。并采用元素分析，’ＨＮＭＲ、ＵＶ－ｖｉｓ、ＩＲ、ＭＳ、摩尔电导、熔点测定进行了化合物的结构表征对配体ｑｍａＨ＿２的金属配合物作了荧光测定。结果表明：配体ｈｐｍａＨ＿４与Ｃｕ（Ⅱ）和Ｃｏ（Ⅱ）配位时，酰胺分别非去质子化和去质子化；配体ｑｍａＨ＿２与金属离子生成类芳香性配合物。由于金属ｄ电子参与芳环π电子的共轭，表现出芳环紫外吸收峰蓝移和荧光性质，尤以Ｚｎ（Ⅱ）配合物最佳；配体ｑｍａＨ＿２与Ｃｏ（Ⅱ）配位时表现出吸氧特性，生成μ－过氧键配合物。
The ligands of N, N’-bis (8-quinolyl) malonamide (qmaH_2), N, N’-bis (2-hydroxyphenyl) malonamide (hpmaH_4) and their metal complexes [M = Cu (II), Ni (II), Co (III), Pd (II), Zn (II)]. The metal complex of qmaH_2 was determined by elemental analysis, structural characterization of ’HNMR, UV-vis, IR, MS, molar conductance and melting point. The results showed that when the ligand hpmaH_4 coordinated with Cu (Ⅱ) and Co (Ⅱ), the amides were not deprotonated and deprotonated respectively. The ligand qmaH_2 and metal ions generated aromatic complexes. Since the d electrons of the metal participate in the conjugation of the aromatic ring π electrons, the blue shift and fluorescence properties of the aromatic ultraviolet absorption peak are shown, especially the Zn (Ⅱ) complex is the best. When the ligand qmaH_2 is coordinated with Co (Ⅱ) Oxygen absorption properties, generating μ-peroxy bond complex.