Lewis酸性离子液体的合成及其催化酯化性能研究

来源 :现代化工 | 被引量 : 0次 | 上传用户：luhaixiong1971

【摘要】

：

以吗啡啉为原料,设计合成了Lewis酸性离子液体[Mor-C4] Br-CuCl2/FeCl3,通过催化合成乙酸乙酯考察了该离子液体的催化活性.结果表明,当n(CH3COOH)∶n(C2H5OH)=0.55∶1、[Mor

【作者】

：

高鹏翔武宇赵地顺翟建华张拴力扈士海

【机构】

：

河北科技大学化学与制药工程学院,河北石家庄,050018;石家庄新宇三阳实业有限公司,河北石家庄,051430

【出处】

：

现代化工

【发表日期】

：

2019年11期

【关键词】

：

Lewis酸性离子液体催化剂酯化反应响应曲面乙酸酯

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

以吗啡啉为原料,设计合成了Lewis酸性离子液体[Mor-C4] Br-CuCl2/FeCl3,通过催化合成乙酸乙酯考察了该离子液体的催化活性.结果表明,当n(CH3COOH)∶n(C2H5OH)=0.55∶1、[Mor-C4] Br-CuCl2/FeCl3质量为醇质量的9.80％、反应温度为83℃、反应时间为4.26 h时,以环己烷为带水剂的收率可达96.58％.离子液体重复使用6次仍具有较高的催化活性.同时以[Mor-C4] Br-CuCl2/FeCl3为催化剂催化合成了系列乙酸酯,获得较高的酯收率.

其他文献

Corrosion Behavior of Cr Micro-alloyed Corrosion-resistant Rebar in Neutral Cl——containing Environme

该文从挂篮荷载计算、施工流程、支座及临时固结施工、挂篮安装及试验、合拢段施工、模板制作安装、钢筋安装、混凝土的浇筑及养生、测量监控等方面人手,介绍了S226海滨大桥

期刊

corrosion-resistant rebarcorrosion behaviorCr micro-alloyingCr-rich rust laye

Effect of Alloying Method on Microstructure and Wear Resistance of Fe-Cr-V-B Based Alloy

The microstructure and wear behavior of Fe-Cr-V-B based alloy was investigated.Each of the specimens was characterized by metallographic techniques and hardness

期刊

microstructureboridecarbidewear resistanceFe-Cr-V-B based alloy

Source and Control of Nitrogen for X70 Pipeline Steel

The effects of some key factors on nitrogen absorption during the smelting process of X70 pipeline steel were studied,and the source of nitrogen pick-up was ana

期刊

nitrogen controlnitrogen absorptionsurface activity elementX70 pipeline steel

Viscosity and Structure Changes of CaO-SiO2-Al2 O3-CaF2 Melts with Substituting Al2 O3 for SiO2

During the smelting process of the high Al steels,the reaction between SiO_2 in molten slag and dissolved aluminum in liquid steel always takes place.This alumi

期刊

high aluminum steelCaO-SiO2-Al2 O3-CaF2viscosityRaman spectrummould flux

Microstructural Evolution and Performance of In-situ Ag-Ni Composite after Solidification under Elec

The effect of electromagnetic stirring(EMS)on microstructure and performance of Ag-8 mass%Ni composite was investigated under both solidified and deformed condi

期刊

Ag-Nielectromagnetic stirringsolidificationin-situ metal matrix composite

Plasma Transferred Arc Surface Alloying of Cr-Ni-Mo Powders on Compacted Graphite Iron

A Cr-Ni-Mo overlayer was deposited on the surface of compacted graphite iron(CGI)by the plasma transferred arc(PTA)alloying technique.The microstructure of Cr-N

期刊

plasma transferred arccompacted graphite ironmicrohardnessfractureNi Cr-Mo c

外源性细胞因子对脑源性神经干细胞分化为神经元的诱导作用

神经干细胞因具有高度自我更新能力、多潜能分化、低免疫原和迁移功能等特征[1],在脑卒中、神经变性等疾病的治疗中显示出良好的应用前景[2~4]。移植的干细胞可以替代缺失的

期刊

外源性细胞因子脑源性神经干细胞分化神经元多潜能分化应用前景神经变性更新能力脑卒中免疫原治疗特征迁移疾病功能

Influences of Technological Parameters on Smelting-separation Process for Metallized Pellets of Vana

The smelting-separation process for metallized pellets of vanadium-bearing titanomagnetite concentrates was studied.The influences of smelting temperature,smelt

期刊

metallized pelletsmeltingseparationtitanium slagvanadiumvanadium-bearing ti

Influence of Mechanical Activation on Acid Leaching Dephosphorization of High-phosphorus Iron Ore Co

High pressure roll grinding(HPRG)and ball milling were compared to investigate the influence of mechanical activation on the acid leaching dephosphorization of

期刊

high-phosphorus iron ore concentratehigh pressure roll grindingball millingse

Curvature and Residual Stress Analysis in Rotational Leveling of Bars

Leveling process plays an important role in delivering the desired material properties and product standards.An analytical method for the rotational leveling pr

期刊

rotational leveling processbarcurvaturetraj ectoryresidual stress

Lewis酸性离子液体的合成及其催化酯化性能研究

与本文相关的学术论文