胆甾醇或薯蓣皂素封端的聚三亚甲基碳酸酯及其液晶性能研究

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【摘要】

：

利用扩链反应活化了胆甾醇或薯蓣皂素端羟基的反应活性,制备了基于胆甾醇或薯蓣皂素衍生物的甾体化合物,并以其为引发剂引发了三亚甲基碳酸酯(TMC)的本体开环聚合反应,制备了胆甾醇或薯蓣皂素封端的聚三亚甲基碳酸酯,采用核磁(1H-NMR)、差示扫描量热仪(DSC)和偏光显微镜(POM)等手段对其结构及液晶性能进行测试表征.结果表明:胆甾基元或薯蓣皂素基的引入赋予了聚三亚甲基碳酸酯液晶性能,且液晶基元的结构对其液晶性能具有显著影响.

【作者】

：

徐孝旭于永鹏陈贵祥陈超先路艳华

【机构】

：

辽东学院化工与机械学院,丹东118003;东北大学分子科学与工程中心,沈阳110004

【出处】

：

高分子通报

【发表日期】

：

2021年11期

【关键词】

：

三亚甲基碳酸酯胆甾醇薯蓣皂素液晶聚合物

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胆甾醇或薯蓣皂素封端的聚三亚甲基碳酸酯及其液晶性能研究

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