The geometric phase, in particular the Berry phase, in an entangled state of five spin-1/2 particles is studied.A time-dependent magnetic field is applied to control the time evolution of the cluster. Using the method of algebraic dynamics, we calculate the non-adiabatic geometric phase or Berry phase and the degeneracy energy levels when the magnetic rotates around Z axis. Based on the exact analytical solutions, we show how the Berry phase of the entangled state of this cluster depends on the exteal magnetic field parameters ω (the angular velocity of the rotating magnetic field) and θ (the angle between the magnetic field and Z axis).