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本文提出了一个适用于有限圆盘电极上多种电化学技术的一般表达式。在可逆情况下,用该方程数值计算得到的电流值与K.Aoki报道的结果相符合,在所有时域内,误差小于0.5%。在不可逆情况下,把该表达式用于诸如线性扫描伏安法、阶梯和方波伏安法等具体技术的详细描述将在下文报道。
This paper presents a general expression for a variety of electrochemical techniques on a finite disk electrode. In the reversible case, the value of this equation is used to calculate the current value and K. The results reported by Aoki are consistent and the error is less than 0.5% in all time domains. A detailed description of the use of this expression for specific techniques such as linear sweep voltammetry, step and square-wave voltammetry in the case of irreversibility will be reported below.