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1 引言近年来,由于掺杂形态的导电聚吡咯的独特的电化学性质和有用性,这类新的化合物颇受人们的关注,但至今作为催化剂用于有机合成中尚不多见。我们做了有益的探试,经用预制的或现域的化学和电化学,催化合成出了多系列多功能的新型的分子簇配合物催化剂(简称P P MC),它们多含过渡金属—有机膦形态的高导有机聚合物,用于催化CO氢化,丙烯和庚烯氢甲酰化制甲醇、正丁醇、辛醇,获得了喜人的催化活性,可观的目的产物的收率,比传统的合成醇方法,条件大为温和和优越,颇有潜在的开发前景。并对作用的理论提出了新见解。
1 Introduction In recent years, due to the unique electrochemical properties and usefulness of the doped conductive polypyrrole, these new compounds are attracting much attention. However, so far, they have not been widely used as catalysts in organic synthesis. We have done a useful exploration to synthesize a series of multi-functional and novel molecular cluster complex catalysts (referred to as PP MC) catalyzed by preformed or field chemical and electrochemical methods. They contain transition metal-organic Phosphine-type, high-conductivity organic polymers have been used to catalyze the hydrogenation of CO and the hydroformylation of propylene and heptene to methanol, n-butanol and octanol, with gratifying catalytic activity, considerable yield of the desired product, Synthetic alcohol method, the conditions for the more moderate and superior, quite potential development prospects. And put forward new ideas on the theory of action.