【摘 要】
：
The title complex[Cp~*Ir{N(Ph_2PS)_2}(N_3)](N(Ph_2PS)_2=bis(diphenylthiophosphoryl)amide,Cp~*=pentamethylcyclopentadienyl)has been prepared and characterized by
【机 构】
：
Material Chemistry Laboratory,Institute of Molecular Engineering and Applied Chemistry
论文部分内容阅读
The title complex[Cp~*Ir{N(Ph_2PS)_2}(N_3)](N(Ph_2PS)_2=bis(diphenylthiophosphoryl)amide,Cp~*=pentamethylcyclopentadienyl)has been prepared and characterized by X-ray diffraction analysis.It crystallizes in monoclinic,space group P2_1/n with a=11.6946(1),b=18.9273(2),c=15.7859(1)(A),β=105.731(1)°,ν=3363.29(5)(A)~3,Z=4,M_r=817.92,D_c=1.615g/cm~3,μ(MoKα)=4.219 mm~(-1),F(000)=1624,S=1.028,the final R=0.0355 and wR=0.0848 for 5987 observed reflections with,I＞2 σ(I) and 363 variables.The molecular structure of 1 consists of discrete monomerie molecule with a distorted octahedral configuration around the iridium atom,having a Cp~* ring at one face and bonded with a chelating bis(diphenylthiophosphoryl)amide group as well as a terminal azido ligand.The average Ir-S and Ir-N bond lengths are 2.416(1)and 2.121(5)(A),respectively.
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