Hydroxypropyl methylcellulose (HPMC) and amphoteric polyacrylamide (ACPAM) were respectively used to prepare engineered cementitious composite (ECC) which exhibits strain-hardening behavior under uniaxial tension. The connections between cement paste structure and the performance of the composite in fresh and hardened state were investigated, aiming at achieving the desirable workability at a given solids concentration. The experimental results of viscosity and microstructure of cement pastes show that the intimate connections between flocculation groups lead to the growing increase in viscosity. The results of deformability and fiber dispersion demonstrate that fiber dispersion coefficient is a comprehensive index which can reflect the performance of deformability as well as uniformity. And the desirable fresh mixture can be achieved by optimizing the viscosity of cement paste. At last, the ductile strain-hardening performance of the ECC prepared with HPMC or ACPAM was investigated through uniaxial tensile test. The connections between cement paste structure and the performance of the composite in fresh and hardened state were (HPMC) investigated, aiming at achieving the desirable workability at a given solids concentration. The experimental results of viscosity and microstructure of cement pastes show that the intimate connections between flocculation groups lead to the growing increase in viscosity. The results of deformability and fiber dispersion demonstrate that fiber At last, the ductile strain-hardening performance of the ECC prepared with HPMC or ACPAM was investigated th rough uniaxial tensile test.