基于酸性条件下溴化钠对NaIO4-H2O2-卡马西平化学发光反应体系具有明显的增敏作用,结合流动注射技术建立了一种测定卡马西平的新方法。在优化的实验条件下,方法的线性范围为1.0×10-9～8.0×10-6g/mL,检出限为3.6×10-10g/mL,相对标准偏差为2.5%(c=2.0×10-7 g/mL,n=11),回收率在98.4%～100.6%间。 Based on acidic conditions sodium bromide sensitized NaIO4-H2O2-carbamazepine chemiluminescence reaction system, a new method for the determination of carbamazepine was developed by using flow injection technique. Under the optimal experimental conditions, the linear range of the method was 1.0 × 10-9 ~ 8.0 × 10-6g / mL with the detection limit of 3.6 × 10-10g / mL and the relative standard deviation of 2.5% (c = 2.0 × 10 -7 g / mL, n = 11). The recoveries ranged from 98.4% to 100.6%.