论文部分内容阅读
本文报告以薯芋皂素降解物双烯醇酮乙酸酯(Ⅳ)为原料,通过高锰酸钾氧化、与苯乙酮缩合、水解和沃氏氧化等反应,合成了目的物(Ⅰ)。并且还合成了△~6-苯甲孕酮(Ⅷ)和△~6,5-苯甲孕酮(X)等衍生物。
In this paper, the objective compound (Ⅰ) was synthesized from the dioxin (IV) acetoacetate (Ⅳ) which is a saponin saponin degradation product by the reaction of potassium permanganate, condensation with acetophenone, hydrolysis and Waugh oxidation. . And also the derivatives of △ 6-progesterone (Ⅷ) and △ 6-propenone (X) were also synthesized.