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用ICB外延技术在NaCl(100)和Si(111)衬底上生长了CdTe单晶薄膜.X光衍射、电子背散射通道及RHEED都表明获得了良好的单晶结构及平滑膜面.外延取向关系为CdTe(100)/NaCl(100)和CdTe(111)/Si(111).实验发现,生长温度小于230℃时,外延膜呈闪锌矿(立方)和钎锌矿(六方)的混合相结构.薄膜生长体现出团粒束淀积的规律,即随着团粒能量的增大,CdTe外延膜的结晶质量显著提高.在Si衬底上,外延得到的最好的CdTe膜,其双晶衍射摆动曲线半高宽为11弧分左右.
CdTe single crystal films were grown on NaCl (100) and Si (111) substrates by ICB epitaxy. X-ray diffraction, electron backscatter channels and RHEED all showed good single crystal structure and smooth film surface. The epitaxial orientation relationship is CdTe (100) / NaCl (100) and CdTe (111) / Si (111). The experimental results show that the epitaxial film is a mixed phase structure of sphalerite (cubic) and wurtzite (hexagonal) when the growth temperature is less than 230 ℃. The film growth reflects the rule of the deposition of agglomerate, that is, with the increase of the energy of the agglomerate, the crystalline quality of the CdTe epitaxial film increases significantly. On the Si substrate, the best epitaxial CdTe film has a full width at half maximum of about 11 arcmin.