Research progresses in the layered double hydroxides [M2+(1-x)M3+x(OH)2]x+An-x/n.mH2O intercalatedwith metal coordinate ions or oxometalates in the last ten years are reviewed. These layered double hydroxides are mainly intercalated with polyoxometalate (POM) ions, a LiAl-LDH photochemical assembly containing TiO2 and CH3(CH2)12COO- anions, together with Zn(TPPC) (porphy-rin derivate) and macrocyclic ligand-containing porphyrin derivate anions. Emphasis is put on the synthesis methods for intercalation of the anions into the interlayer regions, the characterization techniques and structures for the layeredcompounds and the newest research progress in the fields such as catalysis. The review also forecasts the prospects of the field. Research progresses in the layered double hydroxides [M2 + (1-x) M3 + x (OH) 2] x + An-x / n.mH2O intercalated with metal coordinate ions or oxometalates in the last ten years are reviewed. These layered double hydroxides are (TPPC) (porphyrin derivate) and macrocyclic ligand-containing porphyrin derivate anions. Emphasis is put (POM) ions, a LiAl-LDH photochemical assembly containing TiO2 and CH3 on the synthesis methods for intercalation of the anions into the interlayer regions, the characterization techniques and structures for the layeredcompounds and the newest research progress in the fields such as catalysis. The review also forecasts the prospects of the field.