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The complex UO2(DDPEZ)(NO3)2 has been prepared and characterized by IR spectroscopy and XPS spectra. The crystal structure of the complex has been determined by X-ray diffraction. The crystal belongs to Triclinic system and space group P1, with cell parameters: a=0.664 2(3) nm, b=0.805 0(2) nm, c=1.515 6(5) nm, α=104.39(2)°, β=91.13(3)°, γ=94.84(3)°, and V=0.781 4(5) nm3, Z=2, Dc=1 676 kg·m-3, μ(Mo Kα)=0.071 073 nm, F(000)=390, final R=0.037 9 and wR=0.091 7 for observed reflections[I>2σ(I)]. The results indicated that uranyl ion is coordinated with six oxygen atoms, four of them from two nitrate groups and two from carbonyl groups of different organic ligands. CCDC: 284452.
The complex UO2 (DDPEZ) (NO3) 2 has been prepared and characterized by IR spectroscopy and XPS spectra. The crystal structure of the complex has been determined by X-ray diffraction. The crystal belongs to Triclinic system and space group P1, with cell parameters = a = 0.664 2 (3) nm, b = 0.805 0 (2) nm, c = 1.515 6 (5) nm, α = 104.39 (2) °, β = 91.13 (3) °, γ = 94.84 ), And V = 0.781 4 (5) nm3, Z = 2, Dc = 1676 kg · m-3, μ (Mo Kα) = 0.071 073 nm, F (000) = 390, final R = 0.037 9 and wR = 0.091 7 for observed reflections [I> 2σ (I)]. The results indicated that uranyl ion is coordinated with six oxygen atoms, four of them from two nitrate groups and two from carbonyl groups of different organic ligands. CCDC: 284452.