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合成了一种新的基于Anderson结构镍钼酸盐的无机-有机杂化化合物(C3 H7 NO2)2[(H2O)5 (C3 H7 NO2) Ni]2[NiMo6 H6 O24]·2H2O(C3 H7 NO2=β-丙氨酸),通过单晶X射线衍射方法确定了其晶体结构,结构分析表明,该化合物结晶于单斜空间群P21/C,晶胞参数a=1.847 25(13) nm,b=1.059 32(7) nm,c=1.224 77(7) nm,β=104.177(6)°.并对该化合物进行了红外、紫外可见和热重测试,该化合物在苯甲硫醚的催化氧化反应中作为多相催化剂,表现出好的催化活性.“,”A novel Anderson POM-based inorganic-organic hybrid compound (C3 H7 NO2)2 [(H2O)5(C3 H7 NO2) Ni]2 [NiMo6 H6 O24] · 2H2O was synthesized.The crystal structure was characterized by single crystal X-ray crystallography.The structure analysis showed that the compound crystallized in the monoclinic space group P21/c,a=1.847 25 (13) nm,b=1.059 32 (7) nm,c=1.224 77 (7) nm,β=104.177(6)°.The compound was also characterized by IR spectroscopy,UV spectroscopy and TG analysis.The catalytic oxidation reaction of benzenesulfide with the compound as a heterogeneouscatalyst was also studied and the compound exhibited good catalytic activity.