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合成和表征了两种含草酰胺桥的新型异双核配合物[Cu(oxae)Fe(tmen)2]SO4(a)和[Cu(oxpn)Fe(tmen)2]SO4(b)。变温磁化率(4300K)测量和磁分析表明两个Cu(Ⅱ)Fe(Ⅱ)双核配合物中金属离子间有中等强度的反铁磁超交换作用。
Two novel heterobinuclear complexes [Cu (oxae) Fe (tmen) 2] SO4 (a) and [Cu (oxpn) Fe (tmen) 2] SO4 (b) were synthesized and characterized. The measurement of magnetic susceptibility (4300K) and magnetic analysis show that there is moderate intensity of antiferromagnetic meta-exchange between the metal ions in the two Cu (Ⅱ) Fe (Ⅱ) binuclear complexes.