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A novel coordination polymer, [Cu(m-BDOA)(bipy)·H2O]n (m-BDOA2-=benzene-1,3-dioxyacetate), was synthesized and characterized by elemental analysis, IR spectra, X-ray single crystal structure analysis. Crystallographic data are as follows: orthorhombic, space group Pna21, a=1.606 9(3) nm, b=1.685 9(3) nm, c=0.699 7(1) nm, V=1.8955(7) nm3, Z=4, Dc=1.619 g·cm-3, -ligand, two nitrogen atoms of 2,2′-bipy ligand and one coordinated water, there is a distorted square pyramidal environment. Two copper atoms are bridged by m-BDOA2-ligand, forming a one-dimensional chain along a axis. The adjacent distance of Cu...Cu atoms is 0.877 3 nm. The crystal network was formed by the intermolecular hydrogen bond and π-packing interactions.
A novel coordination polymer, [synthesized by characterized by elemental analysis, IR spectra, X-ray single crystal [Cu (m-BDOA) (bipy) · H2O] n (m-BDOA2- = benzene- 1,3-dioxyacetate) (1) nm, c = 0.699 7 (1) nm, V = 1.8955 (7) nm3, b = 1.685 9 (3) nm, Z = 4, Dc = 1.619 g · cm -3, -ligand, two nitrogen atoms of 2,2’-bipy ligand and one coordinated water, there is a distorted square pyramidal environment. Two copper atoms are bridged by m-BDOA2- The adjacent distance of Cu ... Cu atoms is 0.877 3 nm. The crystal network was formed by the intermolecular hydrogen bond and π-packing interactions.