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采用水热方法合成了一种新的三维超分子网络[Ni(PIP)2(N3)2].H2O(1),[PIP=2-苯基咪唑[4,5-f][1,10]菲啰啉],并通过红外和单晶X-射线衍射对其结构进行了表征。结构分析表明,该配合物属三斜晶系,P–1空间群,晶胞参数为:a=8.6955(8),b=13.9232(14),c=15.0982(15),a=115.244(2),β=93.200(2),γ=92.499(2)°,V=1646.2(3)3,Dc=1.512 g.cm-3,Z=2,R1=0.0561,wR2=0.1432.另外,该配合物在室温下表现出黄绿色的荧光性质。
A new three-dimensional supramolecular network [Ni (PIP) 2 (N3) 2] .H2O (1) has been synthesized by a hydrothermal method [PIP = 2-phenylimidazo [4,5-f] ] Phenanthroline], and its structure was characterized by IR and single crystal X-ray diffraction. The structural analysis shows that the complex belongs to the triclinic and P-1 space group with unit cell parameters of a = 8.6955 (8), b = 13.9232 (14), c = 15.0982 2 = β = 93.200 (2) γ = 92.499 (2) ° V = 1646.2 (3) 3 Dc = 1.512 g · cm -3 Z = 2 R1 = 0.0561 wR2 = 0.1432 In addition, The complex shows yellow-green fluorescence at room temperature.