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提出了经验级数自催化反应速率方程和13个派生式的导出途径。导出了描述自催化反应速率曲线特性[αmax和(dα/dt)max]的方程和反应进度(α)随时间(t)和温度(T)变化的方程。编制了计算自催化反应动力学参数(E、A或E1、A1、E2、A2)、经验级数(m、n、p)和αmax、(dα/dt)max值的计算机程序。提出了描述六硝基六氮杂异伍兹烷(HNIW)自催化分解反应的速率方程和硝化棉(NC)(12.82%、12.97%、13.54%、13.61%、13.86%、13.88%、14.14%N)自催化分解反应的动力学参数——催化系数Kcat、速率曲线特性参数和α随t变化的方程。
An empirical rate autocatalytic reaction rate equation and 13 derived derivations are proposed. The equation describing the autocatalytic reaction rate curve characteristic [αmax and (dα / dt) max] and the equation of reaction progress (α) with time (t) and temperature (T) are derived. A computer program was developed to calculate the autocatalytic kinetic parameters (E, A or E1, A1, E2, A2), empirical series (m, n, p) and αmax, (dα / dt) max. The rate equations describing the autocatalytic decomposition of hexanitrohexaazaisowurtzitane (HNIW) and the rate equations of nitrocellulose (NC) (12.82%, 12.97%, 13.54%, 13.61%, 13.86%, 13.88%, 14.14% N ) Kinetic parameters of the autocatalytic decomposition reaction - the catalytic coefficient Kcat, the characteristic parameter of the rate curve and the equation of α as a function of t.